Actually, the AT-ST wouldn't be very good at carrying troops, unless they sat on the roof - its a 2-seater (or 1
Wookiee and a sack-ful of
Ewoks). Its role would more likely be flank protection for larger vehicles and walkers (as seen in
The Empire Strikes Back) and heavy fire support for ground
troops (as seen in
Return of the Jedi).
Scouting is an obvious use, though I personally think it would be a tad too
tall to operate with any
stealth behind enemy lines. But then, stealth doesn't seem to be
the Empire's
forte.