Everything2
Near Matches
Ignore Exact
Full Text
Everything2

leveling effect

created by izubachi

(thing) by izubachi (18 s) (print)   ?   1 C! I like it! Sun Jan 26 2003 at 17:30:21

The leveling effect is a term in physical chemistry to refer to the tendency of any acid or base stronger than a certain threshold to dissociate in a given solvent. All solvents are only capable of handling a maximum strength acid or base. Anything stronger will autoionize to yield something equal to that strongest capable acid/base, or weaker.

As an example, the strongest acid that can exist in water is the hydronium ion, H3O+. Any acid stronger than hydronium will make every effort possible to become hydronium, dissociating. So when one adds hydrochloric acid to water, for example, the reaction goes as follows.

HCl + H2O --> H30+ + Cl-
Hydrochloric acid is much stronger than water, so the leveling effect kicks in and reduces it to hydronium. Likewise for bases, the strongest of which that can exist in water is hydroxide. Throw sodium hydroxide in there aaaand...
NaOH + H2O --> Na+ + OH-
The leveling effect reduces sodium hydroxide to hydroxide and a sodium ion. Although this works with any solvents (and others have much higher thresholds than water), it is most often associated with the principle of aqueous acids and bases. Because of the leveling effect, you don't really have hydrochloric acid or sodium hydroxide floating around in water, as would be predicted by Arrhenius Theory. Instead, you have lots and lots of the threshold acid or base and extra ions capable of forming hydrochloric acid or sodium hydroxide once the water (or any solvent) is removed, as predicted by Brønsted-Lowry Theory.

printable version
chaos

Bronsted-Lowry Theory I Wanna Gain A Level Do like you oughta, add acid to water Will Everything ever stop expanding?
Dash Rendar autoionization Hydroxide Arrhenius Theory
sodium hydroxide hydrochloric acid hydronium base
acid solvent physical chemistry Dissociation
brigandine The Cool War treadmill
Y'know, if you log in, you can write something here, or contact authors directly on the site. Create a New User if you don't already have an account.
  Epicenter
Login
Password

password reminder
register

Everything2 Help

Cool Staff Picks
Little presents from the Node Fairy:
NFL trick plays
fugu
social loafing
crosswalk telepathy
central dogma
Bizarre anti-Semitic interview with Bobby Fischer
It is easier for a camel to go through the eye of a needle
Trail of Tears
Hydrogen engine
Second Punic War
Hittite
Ark of the Covenant
Goldfish
New Writeups
cryforhelp
Major dictionaries of the world(review)
Glowing Fish
The Uncanny X-Men and the New Teen Titans(thing)
WolfKeeper
Launch loop(idea)
TendoKing
Katana(person)
Wuukiee
Highly ornamental cultivars of brambles still have as many thorns as their wild counterparts(idea)
TheDeadGuy
Editor Log: May 2008(log)
everyday j.Lo
pray do not molest them(thing)
ammie
Bands Who Take Their Names from Eighteenth-century English Poetry and Prose(idea)
shaogo
Under My Thumb(review)
ammie
Rock On(person)
The Custodian
The Dresden Files(thing)
Ouzo
PETA becomes you, a proposed future(fiction)
Ereneta
Stone Soup, Part Two(fiction)
jjen
Sorrier than I ever thought I would be(personal)
locke baron
Moskva class antisubmarine cruiser(thing)
This page courtesy of The Everything Development Company